期刊
ACS NANO
卷 9, 期 6, 页码 6383-6393出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsnano.5b01997
关键词
carbon nanotubes; excitons; acoustic phonon localization; isotope effects; dephasing
类别
资金
- National Science Foundation (NSF), CAREER [ECCS-1053537]
- U.S. Department of Energy, Office of Science, Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences [DE-AC36-08GO28308]
- NSF [DMR-0922522]
- U.S. Department of Energy, Office of Basic Energy Sciences [DE-AC02-98CH10886]
- Directorate For Engineering
- Div Of Electrical, Commun & Cyber Sys [1053537] Funding Source: National Science Foundation
Understanding and controlling exciton phonon interactions in carbon nanotubes has important implications for producing efficient nanophotonic devices. Here we show that laser vaporization-grown carbon nanotubes display ultranarrow luminescence line widths (120 mu eV) and well-resolved acoustic phonon sidebands at low temperatures when dispersed with a polyfluorene copolymer. Remarkably, we do not observe a correlation of the zero-phonon line width with C-13 atomic concentration, as would be expected for pure dephasing of excitons with acoustic phonons. We demonstrate that the ultranarrow and phonon sideband-resolved emission spectra can be fully described by a model assuming extrinsic acoustic phonon localization at the nanoscale, which holds down to 6-fold narrower spectral line width compared to previous work. Interestingly, both exciton and acoustic phonon wave functions are strongly spatially localized within 5 nm, possibly mediated by the copolymer backbone, opening future opportunities to engineer dephasing and optical bandwidth for applications in quantum photonics and cavity optomechanics.
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