期刊
CONDENSED MATTER PHYSICS
卷 14, 期 1, 页码 -出版社
INST CONDENSED MATTER PHYSICS NATL ACAD SCIENCES UKRAINE
DOI: 10.5488/CMP.14.13603
关键词
density functional; adsorption; chains; crystals
We investigate the liquid-vapor interface of the restricted primitive model for an ionic fluid using a density functional approach. The applied theory includes the electrostatic contribution to the free energy functional arising from the bulk energy equation of state and the mean spherical approximation for a restricted primitive model, as well as the associative contribution, due to the formation of pairs of ions. We compare the density profiles and the values of the surface tension with previous theoretical approaches.
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