期刊
COMPTES RENDUS CHIMIE
卷 17, 期 4, 页码 342-351出版社
ELSEVIER FRANCE-EDITIONS SCIENTIFIQUES MEDICALES ELSEVIER
DOI: 10.1016/j.crci.2013.09.018
关键词
Silica-microemulsion template; Phase diagram; Phase inversion point; Phase inversion temperature; Inorganic and/or hybrid silica materials
资金
- Sectoral Operational Programme Human Resources Development of the Romanian Ministry of Labour, Family and Social Protection [POSDRU/107/1.5/S/76909]
- ANCS, PN II contract, project acronym NANOLIGHT [C2-07/01.03.2012]
A systematic study of the design and characterization of silica-microemulsion templates is presented. The ternary phase diagrams in micro-heterogeneous systems, by using a nonionic surfactant (Brij 30) and different silica precursors (MTEOS, TEOS, PTEOS), have been drawn. Based on Khalweit diagrams, the phase inversion temperature was estimated as close to 315 K, for both alchil (TEOS) and aril (PTEOS) types of alcoxides. By correlating the information obtained from phase diagrams at room temperature with that of size effects revealed by VIS absorption molecular probes (bromthymol blue dye), the phase inversion point, i.e. the transition point from water-in-oil to oil-in-water microemulsion, was also clearly established as corresponding to R similar to 1. Besides technically attractive features such as a wide variety of inorganic and hybrid nanomaterials, high specific surface and highly efficient applicative properties of the final materials, the approach of silica-microemulsion-based templates can be seen as a route towards the Green Chemistry concept. (C) 2013 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.
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