期刊
COMPTES RENDUS CHIMIE
卷 13, 期 6-7, 页码 803-811出版社
ELSEVIER FRANCE-EDITIONS SCIENTIFIQUES MEDICALES ELSEVIER
DOI: 10.1016/j.crci.2010.03.004
关键词
Uranium; Tripodal ligands; Chelates; Macrocyclic; Diamantane
资金
- DFG through the Sonderforschungsbereich [SFB 583]
The diamantane functional ized triazacyclononane ligand ((Dia)ArOH)(3)tacn (L(3)) has been synthesized and the reactivity of its U(III) metallated product [(((Dia)ArO)(3)tacn)U] (1) has been explored. Complex 1 promotes dichloromethane and azidotrimethylsilane activation to generate U(IV) complex [(((Dia)ArO)(3)tacn)U(Cl] (2) and U(V) complex 1(((Dia)ArO)(3)tacn)U(NTMS)] (3), respectively. Spectroscopic investigations of complexes 1, 2, and 3 will be discussed, along with molecular structures where possible (C) 2010 Published by Elsevier Masson SAS on behalf of Academic des sciences
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