期刊
COMPTES RENDUS CHIMIE
卷 11, 期 8, 页码 805-817出版社
ELSEVIER FRANCE-EDITIONS SCIENTIFIQUES MEDICALES ELSEVIER
DOI: 10.1016/j.crci.2008.01.019
关键词
electrocatalysts; hydrogen oxidation; hydrogen production; proton relays; nickel; iron
The paper presents a review of recent studies of complexes of Ni(II) and Fe(II) coordinated by diphosphine ligands with amine bases incorporated into the ligand chelate rings. The role of the bases in the second coordination sphere in mediating rapid intramolecular M-H/N-H exchange as well as intermolecular exchange with protons and in promoting the coupling of proton- and electron-transfer processes has been studied. Factors that favor efficient proton relay properties for the pendant amines have been established and the information has been used to develop efficient electrocatalysts for both hydrogen oxidation and production.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据