期刊
COMPOSITES SCIENCE AND TECHNOLOGY
卷 71, 期 3, 页码 306-314出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.compscitech.2010.11.015
关键词
Carbon nanotubes; Nano composites; Polymer-matrix composites (PMCs); Electrical properties; Optical microscopy; Dispersion
资金
- German Federal Ministry of Education (BMBF) within the Innovation Alliance Inno.CNT [03X0042 M]
Nanocomposites containing four different polyamide 12 (PA12) types and three grades of multiwalled carbon nanotubes (MWNTs) were prepared via small-scale melt processing to study the effect of different MWNTs and the influence of polymer properties on the dispersion of the fillers and the electrical properties of the composites. Under the selected mixing conditions the lowest electrical percolation threshold of 0.7 wt.% was found for Nanocyl (TM) NC7000 in low viscous PA12. Moreover, big influences of the end group functionality (acid or amine excess) and the melt viscosity of the matrix were found. Composites of PA12 with acid excess showed lower percolation thresholds than those based on amine terminated materials. At constant end group ratio low viscous matrices resulted in lower percolation thresholds than high viscous materials. The best MWNT dispersion was obtained in both high viscous PA12 composites. In these systems the mixing speed was varied indicating an optimum concerning electrical conductivity at 150 rpm as compared to 50 and 250 rpm. (C) 2010 Elsevier Ltd. All rights reserved.
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