Bio-composites of kenaf fibers in polylactide: Role of improved interfacial adhesion in the carding process

Bio-composites comprised of kenaf fiber reinforced polylactide are fabricated by carding followed by treatment with a 3-glycidoxypropyl trimethoxy silane and hot-pressing. The effects of the silane coupling agent on composite properties was highly beneficial leading to increased moduli and heat deflection temperatures as well as reduced water swelling. Swelling is found to increase with increasing kenaf loading levels but to decrease with increasing coupling agent concentrations. Mechanical properties of the biocomposites at tempertaures above the glass transition are vastly improved in comparison to the base PLA polymer. As little as 10 wt.% kenaf fiber in PLA provides a heat distortion temperature in excess of 140 degrees C when combined with the coupling agent. The thermal stability towards degradation is slightly decreased relative to the base PLA and the ash content is increased. Thermal properties such as the glass transition, melting temperature, and percent crystallinity of the matrix PLA are largely unaffected by incorporation into the composites. Evidence of successful reaction of the silane with the kenaf fibers is provided by FTIR and implied by decreased swelling in water. A prototypical automotive headliner is fabricated as a means of demonstrating the viability of the present bio-composites in real manufacturing processes. (C) 2009 Elsevier Ltd. All rights reserved.