High performance cellulose acetate propionate composites reinforced with exfoliated graphene

This paper deals with the preparation, structural characterization, and physical performances of composites composed of biomass-based cellulose acetate propionate (CAP) and exfoliated graphene (EG). As a reinforcing nanofiller, EG is thus prepared by an oxidation/thermal expansion process of natural graphite flakes and it is characterized to consist of disordered graphene platelets. Structural features, thermal stability, mechanical modulus, and electrical resistivity of CAP/EG composites are investigated as a function of EG content. SEM and X-ray diffraction data demonstrate that graphene platelets of EG are well dispersed and exfoliated in the CAP matrix for the composites with up to similar to 1 wt.% EG, although they are partially aggregated in the composites with higher EG contents above similar to 3 wt.%. Thermo-oxidative stability of CAP/EG composites under active oxygen gas condition is improved substantially due to the gas barrier effect of graphene platelets of EG dispersed in the CAP matrix. Dynamic mechanical modulus of the composites is also enhanced significantly with increasing the EG content. This mechanical enhancement of CAP/EG composites is analyzed by adopting the Halpin-Tsai model. The electrical volume resistivity of CAP/EG composites prepared by melt-compounding is decreased dramatically from similar to 10(15) to similar to 10(6) Omega cm by forming the electrical conduction path at a certain EG content between 5 and 7 wt.%. (C) 2012 Elsevier Ltd. All rights reserved.