期刊
COLORATION TECHNOLOGY
卷 129, 期 6, 页码 418-424出版社
WILEY
DOI: 10.1111/cote.12052
关键词
-
资金
- Academy of Scientific Research and Technology, ASRT, Egypt
The main target of this paper was the synthesis of novel azo disperse dyes with better dyeing properties, together with a systematic investigation to determine their dominant tautomer(s) from 12 possible tautomeric structures. In this regard, novel azopyrazolin-5-one dyes were synthesised via the reaction of hydrazine hydrate with 2,3,4-chromantrione-3-arylhydrazones. The acid dissociation constants both in the ground and in the excited state for the series prepared were determined and correlated by the Hammett equation. The results of this correlation, together with spectral data, indicated that the compounds under scrutiny exist predominantly in the keto-hydrazo structure as a Z-configuration, both in the ground and in the excited state. Finally, the synthesised dyes were applied as disperse dyes for dyeing polyester fabrics, and their fastness properties were evaluated. Also, the position of colour in CIELAB coordinates was estimated and discussed.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据