期刊
COLLOIDS AND SURFACES B-BIOINTERFACES
卷 84, 期 2, 页码 454-461出版社
ELSEVIER
DOI: 10.1016/j.colsurfb.2011.01.041
关键词
Chitosan; Prussian blue; Multiwall carbon nanotubes; Hollow PtCo nanochains; Glucose; Electrodeposition
资金
- National Natural Science Foundation of China [20675064]
- Ministry of Education of China [708073]
- Natural Science Foundation of Chongqing City, China [CSTC-2009BA1003]
- Foundation of Southwest University, China [XSGX 02]
In this paper, a simple one-step electrodeposition method is described to fabricate chitosan-Prussian blue-multiwall carbon nanotubes-hollow PtCo nanochains (CS-PB-MWNTs-H-PtCo) film onto the gold electrode surface, then glucose oxidase (GOD) and Nafion were modified onto the film subsequently to fabricate a glucose biosensor. The morphologies and electrochemistry of the composite were investigated by using Fourier transform infrared (FTIR) spectrometry, scanning electron microscopy (SEM) and electrochemical techniques including cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), respectively. The performances of the biosensor have been investigated by chronoamperometry method under the optimized conditions. This biosensor showed a linear response to glucose range from 1.5 mu M to 1.12 mM with a detection limit of 0.47 mu M (S/N =3), a high sensitivity of 23.4 mu A mM(-1) cm(-2), and a fast response time. The apparent Michaelis-Menten constant (K-M(app)) was 1.89 mM. In addition, the biosensor also exhibited strong anti-interference ability, excellent stability and good reproducibility. (C) 2011 Elsevier B.V. All rights reserved.
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