Effect of surfactants on fabricating CuO nanoleaves and Cu nanocages at room temperature

Typical surfactants, cetyltrimethylammonium bromide (CTAB), poly(vinyl pyrrolidone) (PVP) and sodium oleate (SOA), were employed to investigate their effect on fabricating CuO nanoleaves and Cu nanocages at room temperature. Comparing with the system without surfactant, adding surfactant could improve the monodispersity of CuO nanoleaves. The obtained CuO nanoleaves were further reduced to Cu nanocages. CTAB performed few effects on the reduction process. PVP accelerated the reducing velocity, while SOA had inhibitory effect on the reaction. The reaction activities of the obtained Cu nanocages with and without surfactants were characterized by thermo-gravimetric and differential thermal analysis (TG-DTA), and the sequence of activity with oxygen is PVP-assisted Cu > SOA-assisted Cu >CTAB-assisted Cu > Cu without surfactant. The obtained Cu nanocages were also used to construct non-enzymatic glucose sensors. The electrodes modified by PVP- and SOA-assisted Cu had relative higher sensitivity than the others. (C) 2013 Elsevier B.V. All rights reserved.