Effects of hydrostatic pressure on the drag reduction of submerged aerogel-particle coatings

There are several techniques to fabricate superhydrophobic surfaces. The one used in this paper is closer to natural surfaces found, for example, on lotus leaves. Herein, hydrophobic aerogel particles with different average diameters are randomly deposited onto metallic substrates with a thin adhesive coating to achieve a combination of hydrophobicity and surface roughness. The resulting surfaces show different degrees of superhydrophobicity and are used to study the effects of elevated pressure on the drag reduction and the degree of hydrophobicity (survivability) of such surfaces when used for underwater applications. Several previous studies presented numerical and/or analytical models to evaluate the influence of pressure on the superhydrophobicity. Experimental studies, however, are lacking. In this work, we measure the impact of pressure on the stability of the meniscus (air-water interface). The experiments utilize three instruments: (i) a previously developed optical technique to characterize the time-dependent hydrophobicity in conjunction with a pressure vessel in which the submerged coating is exposed to elevated pressures; (ii) a parallel-plate rheometer where the coating's slip length and drag reduction are measured; and (iii) a goniometer to measure the static contact angle as well as contact-angle hysteresis. We also developed an image-thresholding technique to estimate the gas area fraction of the coating. The results indicate that there exists a new parameter, the terminal pressure, beyond which the surface undergoes a global transition from the Cassie state to the Wenzel state, and therefore can no longer generate drag reduction. This terminal pressure differs from the previously identified critical pressure. The latter is the pressure above which the surface starts the transition process at some location, but not necessarily at other spots due to the heterogeneity of the surface. For the particle coatings used herein, the terminal pressures are measured to range from 100 to 600 kPa, indicating that such coatings could potentially be used for deep underwater applications. (c) 2012 Elsevier B.V. All rights reserved.