期刊
COLLOID AND POLYMER SCIENCE
卷 289, 期 10, 页码 1157-1166出版社
SPRINGER
DOI: 10.1007/s00396-011-2441-9
关键词
Isotactic polypropylene; beta-nucleating agent; Cyclodextrin derivative; Crystallization behavior
资金
- Important Item of Science and Technology of Fujian province [2007HZ0001-2]
- Scientific and Technological Personnel Service Enterprise Item of Ministry Science and Technology of China [2009GJC40029]
It was found that lanthanum complex of cyclodextrin derivative (beta-CD-MAH-La) was a highly active beta-nucleating agent for isotactic polypropylene (iPP) in this study. The influence of the nucleating agent on mechanical properties and isothermal and nonisothermal crystallization behavior of iPP has been investigated. Results showed that beta-CD-MAH-La was efficient in inducing the crystallization of iPP into beta-modification (beta-iPP), with K (beta) value of 0.84, while the content of nucleating agent was 0.8 wt.%. beta-iPP could form extensively in the isothermal crystallization temperature range from 110 A degrees C to 140 A degrees C, and the highest amount of beta-crystal content was formed at 130 A degrees C. Besides, it can be known that the addition of beta-CD-MAH-La can obviously facilitate the overall crystallization process of iPP. Under nonisothermal condition, beta-iPP formed at the suitable cooling rates, ranging from 5 A degrees C to 10 A degrees C/min. Furthermore, the nucleation mechanism of beta-CD-MAH-La for iPP was correlated to the special configuration of beta-CD-MAH-La.
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