期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 43, 页码 12748-12752出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201504346
关键词
click chemistry; drug delivery; dye molecules; metal-organic frameworks; molecule capture
资金
- National Research Foundation (NRF), Prime Minister's Office, Singapore through an NRF Fellowship [NRF2009NRF-RF001-015]
- Campus for Research Excellence and Technological Enterprise (CREATE) program-Singapore Peking University Research Centre for a Sustainable Low-Carbon Future
- NTU-A*Star Silicon Technologies Centre of Excellence [11235100003]
- National Natural Science Foundation of China [51322205, 21371014, 11175006]
Three highly porous metal-organic frameworks (MOFs) with a uniform rht-type topological network but hierarchical pores were successfully constructed by the assembly of triazole-containing dendritic hexacarboxylate ligands with Zn-II ions. These transparent MOF crystals present gradually increasing pore sizes upon extension of the length of the organic backbone, as clearly identified by structural analysis and gas-adsorption experiments. The inherent accessibility of the pores to large molecules endows these materials with unique properties for the uptake of large guest molecules. The visible selective adsorption of dye molecules makes these MOFs highly promising porous materials for pore-size-dependent large-molecule capture and separation.
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