期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 6, 页码 2230-2234出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201510495
关键词
electrocatalyst; graphitic carbon; hydrogen evolution; oxygen reduction; Zn-air battery
资金
- NSF [CMMI-1400274, CMMI-1266295, DMR 1106160]
- NSFC [21325415, 21174019, 51433005]
- Directorate For Engineering
- Div Of Civil, Mechanical, & Manufact Inn [1400274, 1266319, 1363123] Funding Source: National Science Foundation
- Directorate For Engineering
- Div Of Civil, Mechanical, & Manufact Inn [1266295] Funding Source: National Science Foundation
The high cost and scarcity of noble metal catalysts, such as Pt, have hindered the hydrogen production from electrochemical water splitting, the oxygen reduction in fuel cells and batteries. Herein, we developed a simple template-free approach to three-dimensional porous carbon networks codoped with nitrogen and phosphorus by pyrolysis of a supermolecular aggregate of self-assembled melamine, phytic acid, and graphene oxide (MPSA/GO). The pyrolyzed MPSA/GO acted as the first metal-free bifunctional catalyst with high activities for both oxygen reduction and hydrogen evolution. Zn-air batteries with the pyrolyzed MPSA/GO air electrode showed a high peak power density (310Wg(-1)) and an excellent durability. Thus, the pyrolyzed MPSA/GO is a promising bifunctional catalyst for renewable energy technologies, particularly regenerative fuel cells.
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