期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 3, 页码 1094-1097出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201508729
关键词
dioxygen activation; metal-free; oxygenation; radical coupling; switchable selectivity
资金
- 973 Program [2012CB725302]
- National Natural Science Foundation of China [21390400, 21520102003, 21272180, 21302148]
- Hubei Province Natural Science Foundation of China [2013CFA081]
- Research Fund for the Doctoral Program of Higher Education of China [20120141130002]
- Ministry of Science and Technology of China [2012YQ120060]
Controlling selectivity is of central importance to radical chemistry. However, the highly reactive and unstable radical intermediates make this task especially challenging. Herein, a strategy for taming radical redox reactions has been developed, in which solvent-bonding can alter the reactivity of the generated radical intermediates and thereby drastically alter the reaction selectivity at room temperature. Various -oxy sulfoxides and -hydroxy sulfides can be facilely obtained, some of which are difficult to synthesize by existing methods. Notably, neither a metal catalyst nor any further additives are necessary in these processes.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据