期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 35, 页码 10299-10302出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201502919
关键词
energetic materials; nitramines; sensitivity; structure elucidation; tetrazoles
资金
- Ludwig-Maximilian University of Munich (LMU)
- Office of Naval Research (ONR) [ONR.N00014-12-1-0538]
Highly energetic 1,5-di(nitramino) tetrazole and its salts were synthesized. The neutral compound is very sensitive and one of the most powerful non-nuclear explosives to date. Selected nitrogen-rich and metal salts were prepared. The potassium salt can be used as a sensitizer in place of tetracene. The obtained compounds were characterized by low-temperature X-ray diffraction, IR and Raman spectroscopy, multinuclear NMR spectroscopy, elemental analysis, and DSC. Calculated energetic performances using the EXPLO5 code based on calculated (CBS-4M) heats of formation and X-ray densities support the high energetic performances of the 1,5-dinitraminotetrazolates as energetic materials. The sensitivities towards impact, friction, and electrostatic discharge were also explored.
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