期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 11, 页码 3417-3430出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201410252
关键词
defects; heterogeneity; industrial chemistry; metal-organic frameworks; secondary building units
资金
- BASF SE (Ludwigshafen, Germany)
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Energy Frontier Research Center [DE-SC0001015]
- U.S. Department of Defense, Defense Threat Reduction Agency [HDTRA 1-12-1-0053]
- King Abdulaziz City of Science and Technology, Riyadh, Saudi Arabia
Metal-organic frameworks (MOFs) are constructed by linking inorganic units with organic linkers to make extended networks. Though more than 20000 MOF structures have been reported most of these are ordered and largely composed of a limited number of different kinds building units, and very few have multiple different building units (heterogeneous). Although heterogeneity and multiplicity is a fundamental characteristic of biological systems, very few synthetic materials incorporate heterogeneity without losing crystalline order. Thus, the question arises: how do we introduce heterogeneity into MOFs without losing their ordered structure? This Review outlines strategies for varying the building units within both the backbone of the MOF and its pores to produce the heterogeneity that is sought after. The impact this heterogeneity imparts on the properties of a MOF is highlighted. We also provide an update on the MOF industry as part of this themed issue for the 150th anniversary of BASF.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据