期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 38, 页码 11050-11053出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201504865
关键词
biofuels; carbon; cellulose depolymerization; glucan hydrolysis; heterogeneous catalysis
资金
- Energy Bioscience Institute
- United States Department of Energy (Basic Energy Sciences) [DE-FG02-05ER15696]
The direct hydrolysis of crystalline cellulose to glucose in water without prior pretreatment enables the transformation of biomass into fuels and chemicals. To understand which features of a solid catalyst are most important for this transformation, the nanoporous carbon material MSC-30 was post-synthetically functionalized by oxidation. The most active catalyst depolymerized crystalline cellulose without prior pretreatment in water, providing glucose in an unprecedented 70% yield. In comparison, virtually no reaction was observed with MSC-30, even when the reaction was conducted in aqueous solution at pH 2. As no direct correlations between the activity of this solid-solid reaction and internal-site characteristics, such as the beta-glu adsorption capacity and the rate of catalytic hydrolysis of adsorbed beta-glu strands, were observed, contacts of the external surface with the cellulose crystal are thought to be key for the overall efficiency.
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