期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 6, 页码 2186-2190出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201509571
关键词
biaryls; chirality; enantioselectivity; hydrazones; palladium
资金
- 973 project [2015CB856600]
- NSFC [21272221, 21472179]
- Recruitment Program of Global Experts
- Fundamental Research Funds for the Central Universities [WK 2060190028, 2060190026]
An efficient palladium-catalyzed asymmetric synthesis of axially chiral vinyl arenes from aryl bromides and hydrazones is reported. The products were easily oxidized to axially chiral biaryl compounds, and the phosphine oxides were readily reduced to phosphine ligands.
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