期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 51, 页码 15540-15544出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201505981
关键词
counterions; fluorine; Michael addition; organocatalysis; rearrangements
资金
- DFG
- DAAD
Aza-ortho-quinone methides allow the straightforward asymmetric synthesis of natural-product-inspired indole scaffolds possessing a quaternary stereocenter. Our approach provides access to diverse communesin and spiroindoline derivatives with high enantioselectivity under mild reaction conditions. Predictable substitution patterns are found to be the key to our regiodivergent protocols.
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