期刊
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
卷 379, 期 -, 页码 226-231出版社
ELSEVIER
DOI: 10.1016/j.jmmm.2014.12.054
关键词
Nanoparticle; Superparamagnetic ferrite; Solvothermal method; Structure guide agent
资金
- State Key Laboratory of Explosion Science and Technology
A series of magnetic iron oxide nanoparticle clusters with different structure guide agents were synthesized by a modified solvothermal method and characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), thermogravimetric analyses (TG), a vibrating sample magnetometer (VSM) and Fourier transform infrared spectroscopy (FTIR). It is found that the superparamagnetic nanoparticles guided by NaCit (sodium citrate) have high saturation magnetization (M-s) of 69.641 emu/g and low retentivity (M-r) of 0.8 emu/g. Guiding to form superparamagnetic clusters with size range of 80-110 nm, the adherent small-molecule citrate groups on the surface prevent the prefabricated ferrite crystals growing further. In contrast, the primary small crystal guided and stabilized by the PVP long-chain molecules assemble freely to larger ones and stop growing in size range of 100-150 nm, which has saturation magnetization (M-s) of 97.979 emu/g and retentivity (M-r) of 46.323 emu/g. The relevant formation mechanisms of the two types of samples are proposed at the end. The superparamagnetic ferrite clusters guided by sodium citrate are expected to be used for movement controlling of passive interference particles to avoid aggregation and the sample guided by PVP will be a candidate of nanometer wave absorbing material. (C) 2014 Elsevier B.V. All rights reserved.
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