期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 23, 页码 6790-6794出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201502094
关键词
heterogeneous catalysis; hydrolysis; metal-organic frameworks; nerve agents; silk fibroin
资金
- Spanish Ministries of Economy [CTQ2011-22787/PPQ, CTQ2014-53486-R]
- Defense (COINCIDENTE)
- MC-IIF (LMRA)
- Junta de Andalucia [P09-FQM-4981]
- ERDF Operative Program of the Region of Murcia
The current technology of air-filtration materials for protection against highly toxic chemicals, that is, chemical-warfare agents, is mainly based on the broad and effective adsorptive properties of hydrophobic activated carbons. However, adsorption does not prevent these materials from behaving as secondary emitters once they are contaminated. Thus, the development of efficient self-cleaning filters is of high interest. Herein, we report how we can take advantage of the improved phosphotriesterase catalytic activity of lithium alkoxide doped zirconium(IV) metal-organic framework (MOF) materials to develop advanced self-detoxifying adsorbents of chemical-warfare agents containing hydrolysable PF, PO, and CCl bonds. Moreover, we also show that it is possible to integrate these materials onto textiles, thereby combining air-permeation properties of the textiles with the self-detoxifying properties of the MOF material.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据