4.8 Article

Condensed-Phase, Halogen-Bonded CF3I and C2F5I Adducts for Perfluoroalkylation Reactions

期刊

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 12, 页码 3712-3716

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201410954

关键词

arenes; C-H functionalization; halogen bonding; pentafluoroethylation; trifluoromethylation

资金

  1. European Community
  2. NSF [CHE-0952753]
  3. Direct For Mathematical & Physical Scien
  4. Division Of Chemistry [0952753] Funding Source: National Science Foundation

向作者/读者索取更多资源

A family of practical, liquid trifluoromethylation and pentafluoroethylation reagents is described. We show how halogen bonding can be used to obtain easily handled liquid reagents from gaseous CF3I and CF3CF2I. The synthetic utility of the new reagents is exemplified by a novel direct arene trifluoromethylation reaction as well as adaptations of other perfluoroalkylation reactions.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.8
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据