期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 13, 页码 4065-4069出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201411807
关键词
C-H activation; fluorine; radicals; synthetic methods; trifluoromethylthiolation
资金
- State Key Laboratory of Elemento-Organic Chemistry
- 1000 Youth Talents Plan
- NSFC [21402098, 21421062]
- Natural Science Foundation of Tianjin [13JCYBJC36500]
The first example of a practical and direct trifluoromethylthiolation reaction of unactivated aliphatic C-H bonds employs a silver-based reagent. The reaction is operationally simple, scalable, and proceeds under aqueous conditions in air. Furthermore, its broad scope and good functional-group compatibility were demonstrated by applying this method to the selective trifluoromethylthiolation of natural products and natural-product derivatives.
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