期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 44, 页码 12973-12975出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201506744
关键词
1,2,3,4-tetrazines; 1,2,4-triazoles; amination; oxidation; energetic materials
资金
- Joint Munitions Technolgy Development Program
- U.S. Department of Energy [DE-AC52-06A25396]
- Office of Naval Research [N00014-11-AF-0-0002]
This study presents the synthesis and characterization of a fused, tricyclic 1,2,3,4-tetrazine ring system. The molecule is synthesized in a three-step process from 5,5-dinitro-bis,1,2,4-triazole via a di-N-amino compound. Oxidation to form the azo-coupled fused tricyclic 1,2,3,4-tetrazine is achieved using tert-butyl hypochlorite as the oxidant. The di-N-amino compound and the desired fused tricyclic 1,2,3,4-triazine display interesting thermal behavior and are predicted to be high-performance energetic materials.
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