期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 51, 页码 15483-15487出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201505508
关键词
CO2 capture; confinement; ionic liquids; molecular sieving; ZIF-8
资金
- National Science Fund [21176231, 21006101, 21276249, 21136001, 21322603]
- Chinese Academy of Science [KGZD-EW-T05]
Fine-tuning of effective pore size of microporous materials is necessary to achieve precise molecular sieving properties. Herein, we demonstrate that room temperature ionic liquids can be used as cavity occupants for modification of the microenvironment of MOF nanocages. Targeting CO2 capture applications, we tailored the effective cage size of ZIF-8 to be between CO2 and N-2 by confining an imidazoliumbased ionic liquid [bmim][Tf2N] into ZIF-8's SOD cages by in-situ ionothermal synthesis. Mixed matrix membranes derived from ionic liquid-modified ZIF-8 exhibited remarkable combinations of permeability and selectivity that transcend the upper bound of polymer membranes for CO2/N-2 and CO2/CH4 separation. We observed an unusual response of the membranes to varying pressure, that is, an increase in the CO2/CH4 separation factor with pressure, which is highly desirable for practical applications in natural gas upgrading.
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