期刊
JOURNAL OF LUMINESCENCE
卷 167, 期 -, 页码 146-155出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jlumin.2015.06.027
关键词
Phenazine; Indenofuran; Fluorescence; Absorbance
类别
资金
- CSIR, New Delhi, India
A new fluorescent sensor 10a,15a-dihydroxy-10aH-benzo[a]indeno[2',1':4,5]furo[2,3-c]phenazin-15 (15aH)-one (1) based on the combination of phenazine and indenofuran moieties was designed and synthesized. Structure of the synthesized sensor has been confirmed by X-ray crystallographic analysis. Absorption and emission spectra of 1 has been studied in solvents of different polarity. The solvent effect on the spectral properties of I has been investigated by using the Lippert-Mataga and Reichardt-Dim-roth methods. It exhibits high sensitivity and selectivity towards Cu2+ and Pb2+ ions over other metal ions by fluorescence quenching. Sensor 1 exhibited a visible color change from light orange to pink, and yellow in the presence of Cu2+ and Pb2+, respectively. The fluorescence of the 1-Cu2+/Pb2+ complexes can be reversibly restored to that of the uncomplexed ligand by using EDTA. Binding stoichiometry and mechanism of Cu2+ and Pb2+ ions detection have been investigated. The linear range for the synthesized sensor was found to be 1 x 10(-6)-6.31 x 10(-5) M with detection limit of 1.3 x 10(-6) M. Theoretical calculations were employed to understand the sensing mechanism of the sensors towards Cu2+. (C) 2015 Elsevier B.V. All rights reserved.
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