期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 38, 页码 11205-11208出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201504697
关键词
asymmetric catalysis; carbenoids; chiral phosphoric acids; gold; indolinones
资金
- National Natural Science Foundation of P. R. China [21372202, 21402175]
- New Century Excellent Talents in University [NCET-12-1086]
- Zhejiang Natural Science Fund [R14B020005]
The enantioselective redox annulation of nitro-alkynes with indoles is enabled by gold/chiral phosphoric acid dual catalysis. A range of indolin-3-one derivatives bearing quaternary stereocenters at the C2 position were afforded in good yields and excellent enantioselectivities (up to 96% ee) from readily available starting materials.
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