期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 4, 页码 1295-1298出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201507697
关键词
arylation; B-H activation; carborane; coupling reactions; homogeneous catalysis
资金
- Research Grants Council of The Hong Kong Special Administration Region [CUHK7/CRF/12G, 14306114]
- National Basic Research Program of China (973 Program) [2012CB821600]
- NSFC/RGC [N-CUHK442/14]
Palladium-catalyzed intermolecular coupling of o-carborane with aromatics by direct cage B-H bond activation has been achieved, leading to the synthesis of a series of cage B(4,5)-diarylated-o-carboranes in high yields with excellent regioselectivity. Traceless directing group -COOH plays a crucial role for site-and di-selectivity of such intermolecular coupling reaction. A Pd-II-Pd-IV-Pd-II catalytic cycle is proposed to be responsible for the stepwise arylation.
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