An Aligned and Laminated Nanostructured Carbon Hybrid Cathode for High-Performance Lithium-Sulfur Batteries

An aligned and laminated sulfur-absorbed mesoporous carbon/carbon nanotube (CNT) hybrid cathode has been developed for lithium-sulfur batteries with high performance. The mesoporous carbon acts as sulfur host and suppresses the diffusion of polysulfide, while the CNT network anchors the sulfur-absorbed mesoporous carbon particles, providing pathways for rapid electron transport, alleviating polysulfide migration and enabling a high flexibility. The resulting lithium-sulfur battery delivers a high capacity of 1226mAhg(-1) and achieves a capacity retention of 75% after 100 cycles at 0.1C. Moreover, a high capacity of nearly 900mAhg(-1) is obtained for 20mgcm(-2), which is the highest sulfur load to the best of our knowledge. More importantly, the aligned and laminated hybrid cathode endows the battery with high flexibility and its electrochemical performances are well maintained under bending and after being folded for 500 times.