期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 8, 页码 2543-2547出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201411272
关键词
homochiral aggregates; porphyrinoids; self-assembly; subphthalocyanine; supramolecular polymerization
资金
- MINECO [CTQ2011-24187, CTQ2011-23659, MAT2012-38538-CO3-01, MAT2012-38538-CO3-02]
- MINECO (FEDER funds) [CTQ2012-31914, CTQ2012-35513-C02-01]
- CAM [S2013/MIT-2841 FOTO-CARBON]
- GVA [PROMETEO/2012/053]
- GVA (European Research Council) [StG-279548]
- MECD
A combination of spectroscopy (UV/Vis absorption, emission, and circular dichroism), microscopy (AFM and TEM), and computational studies reveal the formation of non-centrosymmetric homochiral columnar subphthalocyanine assemblies. These assemblies form through a cooperative supramolecular polymerization process driven by hydrogen-bonding between amide groups, - stacking, and dipolar interactions between axial BF bonds.
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