期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 27, 页码 7920-7923出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201501538
关键词
allenes; carbenes; copper; diazo compounds; flow chemistry
资金
- Cambridge Home and European Scholarship Scheme
- Swiss National Science Foundation
- Pfizer Worldwide Research and Development
- EPSRC [EP/K0099494/1, EP/K039520/1]
- EPSRC [EP/K009494/1, EP/K039520/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/K039520/1, EP/K009494/1] Funding Source: researchfish
A copper-catalyzed coupling reaction between flow-generated unstabilized diazo compounds and terminal alkynes provides di- and trisubstituted allenes. This extremely mild and rapid transformation is highly tolerant of several functional groups.
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