期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 31, 页码 8984-8987出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201502957
关键词
artificial muscles; host-guest systems; self-healing; shape memory; supramolecular gels
资金
- ImPACT Program of the Council for Science, Technology, and Innovation (Cabinet Office, Government of Japan)
- MEXT of Japan [2206, 26288062]
- Grants-in-Aid for Scientific Research [26288062, 15J30006] Funding Source: KAKEN
Supramolecular materials cross-linked between polymer chains by noncovalent bonds have the potential to provide dynamic functions that are not produced by covalently cross-linked polymeric materials. We focused on the formation of supramolecular polymeric materials through host-guest interactions: a powerful method for the creation of nonconventional materials. We employed two different kinds of host-guest inclusion complexes of -cyclodextrin (CD) with adamantane (Ad) and ferrocene (Fc) to bind polymers together to form a supramolecular hydrogel (CD-Ad-Fc gel). The CD-Ad-Fc gel showed self-healing ability when damaged and responded to redox stimuli by expansion or contraction. Moreover, the CD-Ad-Fc gel showed a redox-responsive shape-morphing effect. We thus succeeded in deriving three functions from the introduction of two kinds of functional units into a supramolecular material.
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