期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 14, 页码 4259-4263出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201500207
关键词
membranes; metal-organic frameworks; photochemistry; polymerization; separation capacity
资金
- 973 Program [2013CB834704]
- Provincial Key Project of China [7131253]
- National Natural Science Foundation of China [21471018, 21404010, 21201018]
- 1000 Plan (Youth)
Metal-organic frameworks (MOFs) are a promising class of nanoporous polymeric materials. However, the processing of such fragile crystalline powders into desired shapes for further applications is often difficult. A photoinduced postsynthetic polymerization (PSP) strategy was now employed to covalently link MOF crystals by flexible polymer chains, thus endowing the MOF powders with processability and flexibility. Nanosized UiO-66-NH2 was first functionalized with polymerizable functional groups, and its subsequent copolymerization with monomers was easily induced by UV light under solvent-free and mild conditions. Because of the improved interaction between MOF particles and polymer chains, the resulting stand-alone and elastic MOF-based PSP-derived membranes possess crack-free and uniform structures and outstanding separation capabilities for Cr-VI ions from water.
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