期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 47, 页码 14187-14189出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201508500
关键词
alkaloids; nitrogen heterocycles; sustainable chemistry; total synthesis; xylochemistry
资金
- Carl Zeiss Foundation
- University of Alabama [RG14648]
The first total synthesis of the dimeric berberine alkaloid ilicifoline (ilicifoline B) is reported. Its carbon skeleton is constructed from ferulic acid, veratrole, and methanol. The synthesis reported herein employs starting materials solely derived from wood. The natural product is thus constructed entirely from renewable resources. The same strategy is applied to a formal total synthesis of morphinan alkaloids. The use of wood-derived building blocks (xylo-chemicals) instead of the conventional petrochemicals represents a sustainable alternative to classical synthetic approaches.
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