期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 15, 页码 4531-4534出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201411334
关键词
density functional calculations; flow chemistry; radicals; rearrangements; small ring systems
资金
- GlaxoSmithKline
- EPSRC
- ERDF [4061, 4494, 4196]
- Engineering and Physical Sciences Research Council [EP/C006364/1] Funding Source: researchfish
- EPSRC [EP/C006364/1] Funding Source: UKRI
Diradical intermediates, formed by thermolysis of alkynylcyclobutenones, can display radical, anion, or electrophilic character because of the existence of an orbital isomer with zwitterionic and cyclohexatrienone character. Our realization that water, alcohols, and certain substituents can induce the switch provides new opportunities in synthesis. For example, it can be used to shut down radical pathways and to give access to aryl carbonates and tetrasubstituted quinones.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据