期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 19, 页码 5583-5587出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201410664
关键词
hexacyanomanganate; long-range order; magnetic tape; single-chain magnets
资金
- Department of Energy [DE-FG02-02ER45999]
- U.S. Department of Energy (DOE) [DE-FG02-02ER45999] Funding Source: U.S. Department of Energy (DOE)
The tape-like chain {[(tptz)Mn-II(H2O)-Mn-III(CN)(6)](2)Mn-II(H2O)(2)}(n)center dot 4nMeOH center dot 2nH(2)O based on the anisotropic building block hexacyanomanganate(III) exhibits long-range magnetic ordering below 5.1 K as well as single-chain magnetic behavior at lower temperatures with an effective energy barrier of 40.5(7) K.
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