期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 29, 页码 8411-8414出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201500994
关键词
halocarbon compounds; halogen bonding; host-guest interactions; molecular recognition; self-assembly
资金
- FIRB/MIUR (FLUORIMAGING)
- JSPS
- [24000009]
- [25708008]
- Grants-in-Aid for Scientific Research [24000009, 25708008] Funding Source: KAKEN
The confined space inside a self-assembled cage enhanced halogen bonding (XB) between iodoperfluorocarbons (XB donors) and NO3- anions or H2O molecules (XB acceptors), as confirmed by NMR spectroscopy in solution and by X-ray crystallography in the solid state. The cavity also bound an XB donor-acceptor pair, C6F3I3 and C6H5NMe2, in a selective pairwise fashion.
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