期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 35, 页码 10341-10346出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201500392
关键词
carbon nanotubes; cycloparaphenylene; macrocycles; polycyclic aromatic hydrocarbons; Scholl reaction
资金
- EU [FP 7 256617 MOLESOL]
- DFG [MU 334/36-1]
- Graduate School MAINZ
The longitudinal extension of cycloparaphenylenes (CPP) towards ultrashort carbon nanotubes (CNTs) is essential for the solution based bottom-up synthesis of CNTs. Herein, the longitudinal extension of the CPP skeleton by the introduction of hexaphenylbenzene units towards polyarylated [n]CPPs is described. Further, the applicability of the Scholl reaction to selectively form graphenic sidewalls is demonstrated. The ring size and substitution patterns of the polyarylated [n]CPPs were varied to overcome strain-induced side reactions during the oxidative cyclodehydrogenation and cyclic para-hexa-peri-hexabenzocoronene trimers ([3]CHBCs) were selectively obtained. This concept is envisioned as an access to ultrashort carbon nanotubes subject to the condition that further benzene rings with the right connectivity will be inserted.
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