期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 51, 页码 15493-15496出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201508501
关键词
acylsilanes; carbenes; C-H functionalization; heterocyclic chemistry; iridium catalysis
Exposing ortho-amido aroylsilanes to visible light or heat leads to cyclization reactions that provide N-heterocyclic compounds via siloxycarbenes as key intermediates. The previously unreported starting materials have been prepared by directed amidations of aromatic acylsilanes in the presence of an iridium catalyst followed by N-alkylation.
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