期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 9, 页码 2729-2733出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201410557
关键词
amino acids; asymmetric catalysis; bioinspired catalysis; epoxidation; non-heme iron complexes
资金
- European Research Council [ERC-2009-StG-239910]
- MINECO of Spain [CTQ2012-37420-C02-01/BQU, CSD2010-00065]
- Generalitat de Catalunya [2009SGR637]
- MICINN
Highly enantioselective epoxidation of -substituted styrenes with aqueous H2O2 is described by using a chiral iron complex as the catalyst and N-protected amino acids (AAs) as coligands. The amino acids synergistically cooperate with the iron center in promoting an efficient activation of H2O2 to catalyze epoxidation of this challenging class of substrates with good yields and stereoselectivities (up to 97%ee) in short reaction times.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据