期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 55, 期 4, 页码 1561-1564出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201509963
关键词
cage compounds; corannulenes; host-guest systems; supramolecular chemistry; pi interactions
资金
- KAKENHI, MEXT [24000009]
- Alexander von Humboldt Foundation
- JSPS [P-14744]
- Grants-in-Aid for Scientific Research [14F04744, 26102508, 24000009] Funding Source: KAKEN
Self-assembled coordination cages can be employed as a molecular press, where the bowl-shaped guest corannulene (C20H10) is significantly flattened upon inclusion within the hydrophobic cavity. This is demonstrated by the pairwise inclusion of corannulene with naphthalene diimide as well as by the dimer inclusion of bromocorannulene inside the boxlike host. The compressed corannulene structures are unambiguously revealed by single-crystal X-ray analysis.
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