期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 24, 页码 7181-7184出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201502180
关键词
aggregation-induced emission; delayed fluorescence; dual emission; white-light emission
资金
- NSF of China [51173210, 51473185]
- c863 Programgs [SS2015AA031701]
- Fundamental Research Funds for the Central Universities
A novel white-light-emitting organic molecule, which consists of carbazolyl-and phenothiazinyl-substituted benzophenone (OPC) and exhibits aggregation-induced emission-delayed fluorescence (AIE-DF) and mechanofluorochromic properties was synthesized. The CIE color coordinates of OPC were directly measured with a non-doped powder, which presented white-emission coordinates (0.33, 0.33) at 244 K to 252 K and (0.35, 0.35) at 298 K. The asymmetric donor acceptor-donor' (D-A-D') type of OPC exhibits an accurate inherited relationship from dicarbazolyl-substituted benzophenone (O2C, D-A-D) and diphenothiazinyl-substituted benzophenone (O2P, D'-A-D'). By purposefully selecting the two parent molecules, that is, O2C (blue) and O2P (yellow), the white-light emission of OPC can be achieved in a single molecule. This finding provides a feasible molecular strategy to design new AIE-DF white-light-emitting organic molecules.
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