期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 19, 页码 5772-5776出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201411997
关键词
C-H functionalization; disulfides; heteroarenes; heterogeneous catalysis; thiolation
资金
- Deutsche Forschungsgemeinschaft [SFB 858]
The first general methodology for the direct thiolation of electron-rich heteroarenes was developed by employing Pd/Al2O3, a recoverable and commercially available heterogeneous catalyst, and CuCl2. This method represents an operationally simple approach for the synthesis of these valuable compounds. Preliminary mechanistic studies indicate a heterogeneous catalytic system, in which both metals play a complementary role in the formation of the thiolated products.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据