期刊
CHIRALITY
卷 22, 期 9, 页码 827-837出版社
WILEY
DOI: 10.1002/chir.20843
关键词
oxidative coupling; enantioselective synthesis; chiral ligand; BINOLs
资金
- Scientific Research Foundation of the Education Ministry for Returned Chinese Scholars, Fudan University Youth Scientific Foundation
The enantiomeric atropoisomers of 1,10-binaphthyl-2,20-diol (BINOL) have become one of the most widely used chiral ligands and auxiliaries for asymmetric synthesis. This review provides an overview of enantioselective synthesis of optical active BINOLs by straightforward asymmetric oxidative coupling of identical 2-naphthol and its substituted derivatives. Chirality 22:827-837, 2010. (C) 2010 Wiley-Liss, Inc.
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