期刊
CHIRALITY
卷 21, 期 1, 页码 2-5出版社
WILEY
DOI: 10.1002/chir.20565
关键词
carboranes; phosphites; asymmetric hydrogenation; electronic effect
资金
- Division of General Chemistry and Material Science of the Russian Academy of Sciences, INTAS [05-1000008-8064]
- ISTC [3477]
A series of new fine-tunable monodentate phosphite and phosphoramidite ligands based on carboranes have been synthesized and used for asymmetric Rh-catalyzed hydrogenation of prochiral olefins with the result of up to 99.8% ee. Dependence of the enantio selectivity on the electron-withdrawing or electron-donating properties of the carboranyl substituent has been studied. Chirality 21:2-5, 2009. (C) 2008 Wiley-Liss, Inc.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据