期刊
CHIRALITY
卷 20, 期 5, 页码 749-759出版社
WILEY
DOI: 10.1002/chir.20482
关键词
cholesteric induction; absolute configuration; liquid crystal; nematic helical twisting power
Doping nematic liquid crystals with nonracemic chiral compounds induces a twisted nematic (cholesteric) phase. The ability of solutes to twist the nematic phase may be related to the overall shape of the chiral dopant and consequently to its absolute configuration. The cholesteric induction is therefore a powerful tool complementary to chiroptical techniques to obtain stereochemical information on chiral molecules.
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