期刊
CHINESE SCIENCE BULLETIN
卷 56, 期 36, 页码 3988-3992出版社
SCIENCE PRESS
DOI: 10.1007/s11434-011-4781-8
关键词
amorphous alloys; azo dyes; UV-visible spectrophotometer; degradation; activation energy
资金
- Ministry of Science and Technology of China [2011CB606301]
- National Natural Science Foundation of China [50825402]
An Fe-based amorphous alloy was found to significantly enhance the reductive degradation of an azo dye in aqueous solution. The surface-area normalized rate constant was up to 2.0 L m(-2) min(-1) at room temperature, an order of magnitude larger than any previously reported value. The activation energy of the degradation process was calculated according to the Arrhenius equation, and a much lower value than those previously reported was obtained. Valence band measurement indicated that a depressed valence band maximum and a widened empty band were established in the amorphous ribbon. The unique structure of the amorphous alloy is important - it may reduce the activation energy of the degradation process and enhance the activity of the electrons, thus accelerating the degradation process.
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