期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 17, 页码 5098-5102出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201500570
关键词
beta-diketiminate; bond activation; carbon dioxide; cooperative reactivity; gallium
资金
- EPSRC [EP/L025000/1, EP/K014714/1]
- EPSRC [EP/K014714/1, EP/L025000/1, EP/K014668/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/K014668/1, EP/L025000/1, EP/K014714/1] Funding Source: researchfish
A single-component ambiphilic system capable of the cooperative activation of protic, hydridic and apolar H-X bonds across a Group 13 metal/activated beta-diketiminato (Nacnac) ligand framework is reported. The hydride complex derived from the activation of H-2 is shown to be a competent catalyst for the highly selective reduction of CO2 to a methanol derivative. To our knowledge, this process represents the first example of a reduction process of this type catalyzed by a molecular gallium complex.
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